A Model of the Chemical Vapor Deposition of SiGe films from Silane and Germane

Matthew Stoker ( matt-DOT-stoker-AT-motorola-DOT-com.gif ), Tushar Merchant, Andrew Morton and Jill Hildreth
Advanced Modeling and Simulation, Motorola, Mesa, AZ 85202, USA

A model has been developed for the chemical vapor deposition of epitaxial Si1-xGex films from SiH4 and GeH4. The model is based on a simplified chemical mechanism including adsorption and decomposition of SiH4, GeH4 and H2 on vacant Si or Ge sites and subsequent H2 desorption. The model focuses on effects at relatively high pressures (i.e. 1-200 Torr) where suppression of deposition by adsorbed hydrogen becomes important, resulting in an inverse dependence of the deposition rate on pressure. In addition as the pressure is increased the Ge concentration of the film is observed to become strongly dependent on temperature. The model assumes that this temperature dependence is due to the influence of adsorbed hydrogen on segregation of Ge to the surface and the relative concentration of vacant Si and Ge sites. The model predictions of deposition rate and Ge concentration compare favorably with experimental data over a wide range of conditions.