A Model of the Chemical Vapor Deposition of SiGe films from Silane and Germane
Matthew Stoker (
),
Tushar Merchant,
Andrew Morton and Jill Hildreth
Advanced Modeling and Simulation, Motorola, Mesa, AZ 85202, USA
A model has been developed for the chemical vapor deposition of epitaxial
Si1-xGex films from SiH4 and GeH4. The model is based on a simplified
chemical mechanism including adsorption and decomposition of SiH4, GeH4 and H2
on vacant Si or Ge sites and subsequent H2 desorption. The model focuses on
effects at relatively high pressures (i.e. 1-200 Torr) where suppression of
deposition by adsorbed hydrogen becomes important, resulting in an inverse
dependence of the deposition rate on pressure. In addition as the pressure is
increased the Ge concentration of the film is observed to become strongly
dependent on temperature. The model assumes that this temperature dependence
is due to the influence of adsorbed hydrogen on segregation of Ge to the
surface and the relative concentration of vacant Si and Ge sites. The model
predictions of deposition rate and Ge concentration compare favorably with
experimental data over a wide range of conditions.