Nonlinear dynamic susceptibilities of superparamagnetic nanoparticles
Yu. L. Raikher (

),
V. I. Stepanov,
Institute of Continuum Media Mechanics, 1 Korolyev St., 614013, Perm, Russia.
Consistent nonlinear extension of the superparamagnetic response theory is
constructed on the basis of the rotary diffusion equation governing the
precession and relaxation of the magnetic moment in a single-domain particle
in the presence of thermal fluctuations. Along with the linear one, we
determine the third- and fifth-order susceptibilities to an arbitrarily
directed field by a numerical procedure that takes into account the full set
of the magnetic moment relaxation modes, i.e., fast intrawell and slow
interwell ones. To get to real samples, the averagings over the particle
volumes and anisotropy axes distribution are performed. The results were
quantitatively tested on the measurements of the cubic susceptibility of
nanocrystalline CuCo alloys, where more simple models miss the goal. Also, for
the mentioned situations, using numerical solutions as an quality check, we
construct compact and accurate semi-heuristic formulas very feasible for
experiment interpretation.Another analytical tool that we derive and that is
very handy for theory and experiment is the high-barrier approximation. It
works when the ratio S of the magnetic anisotropy energy to temperature, is
high. Then the magnetic relaxation is rather slow, and one may say that the
particles are becoming quasi-permanent magnets. When treated numerically, this
case is the most resource-consuming one. Expanding the micromagnetic equation
with respect to 1/S, we get the solutions in the form of asymptotic series, of
which the set of dynamic susceptibilities is constructed. The emerging
expressions appear to be both very simple and very accurate in the S > 1
range.
Partial financial support from Award PE-009-0 from CRDF and Project 97-31311
from INTAS is gratefully acknowledged.